It looks like you have started a meeting (the toolbar in the left-right corner of your screenshot).
Also it seems you have joined (in parallel) to another meeting (green window). And that another meeting is not started yet, so you are in "waiting room" (green window), waiting until meeting is started by someone.
I hope it helps.
This doesn't help. Just tried it. After then starting a new meeting I find myself in the waitingroom again.
In fact I can start a meeting with a participant but the green window remains. I see the videos only in mini size in the Blizz panel.